The MSDS of PYRETHRUM 50%

- Apr 11, 2018 -

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name PYRETHRUM 50%

 

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Supplier PANPAN INDUSTRY CO., LIMITED

RM308, Building NO.9, National University Technology Zone, Zhengzhou, Henan, China

Tel: 0086-371-60383117

1.4. Emergency telephone number

Tel: 0086-371-60383117

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (1999/45/EEC) Xi;R41. N;R50/53.

2.2. Label elements

Labelling

Risk Phrases

R41---------- Risk of serious damage to eyes.

R50/53------ Very toxic to aquatic organisms,  may cause long-term adverse effects in the

aquatic environment.

Safety Phrases

S2----------- Keep out of the reach of children.

S13---------- Keep away from food,  drink and animal feeding stuffs.

S20/21------ When using do not eat,  drink or smoke.

S23---------- Do not breathe vapour/spray.

S26---------- In case of contact with eyes,  rinse immediately with plenty of water and seek

medical advice.

S35 ----------This material and its container must be disposed of in a safe way.

S39------------ Wear eye/face protection.

S57------------ Use appropriate containment to avoid environmental contamination.

S23 -------------Do not breathe spray.

            Do not breathe smoke/fumes.

2.3. Other hazards

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Content

图片4.png 

 

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Move the exposed person to fresh air at once.

Ingestion

DO NOT induce vomiting.  Get medical attention immediately.

Skin contact

Wash skin thoroughly with soap and water.

Eye contact

Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

 

SECTION 5: FIREFIGHTING MEASURES

 

5.1. Extinguishing media

Extinguishing media

Water spray,  foam,  dry powder or carbon dioxide.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards

No unusual fire or explosion hazards noted.

Specific hazards

When heated and in case of fire,  toxic vapours/gases may be formed. When heated and in case of fire,  irritating vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures

Keep run-off water out of sewers and water sources. Dike for water control. Dike and collect extinguishing water.  If risk of water pollution

occurs,  notify appropriate authorities.

 

SECTION 6: ACCIDENTAL RELEASE MEASURES

 

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

Do not discharge into drains,  water courses or onto the ground.

6.3. Methods and material for containment and cleaning up

Absorb in vermiculite,  dry sand or earth and place into containers.

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling,  skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

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8.2. Exposure controls

Protective equipment

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Respiratory equipment

 

No specific recommendation made,  but respiratory protection may still be required under exceptional circumstances when excessive air

contamination exists.

Hand protection

 

Protective gloves are recommended.

 

Eye protection

Use eye protection.

 

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

 

9.1. Information on basic physical and chemical properties

Appearance------------------------ Liquid

Colour------------------------------ Brown.

Odour------------------------------- Slight odour.

Solubility ---------------------------in soluble water,be easily resolved in ethanol, methanol 

Relative density------------------- 0.85-1.01

pH-Value, Conc. Solution--------- 4-7

9.2. Other information

 

SECTION 10: STABILITY AND REACTIVITY

 

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

 

SECTION 11: TOXICOLOGICAL INFORMATION

 

11.1. Information on toxicological effects

Toxic Dose 1 - LD 50 Pyrethrins: 900-2000 mg/kg (oral rat)

Toxic Dose 2 - LD 50 Piperonyl Butoxide: 7500 mg/kg (oral rat)

Inhalation

May cause irritation to the respiratory system.

Ingestion

May cause irritation to throat and stomach.

Skin contact

Liquid may irritate skin.  Prolonged contact may cause redness,  irritation and dry skin.

Eye contact

Irritating and may cause redness and pain.

 

SECTION 12: ECOLOGICAL INFORMATION

 

Ecotoxicity

The product contains a substance which is harmful to aquatic organisms.

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

 

SECTION 13: DISPOSAL CONSIDERATIONS

 

13.1. Waste treatment methods

This material and its container must be disposed of in a safe way. Do not allow runoff to sewer,  waterway or ground.

 

SECTION 14: TRANSPORT INFORMATION

 

14.1. UN number

UN No. (ADR/RID/ADN)------- 3082

UN No. (IMDG)------------------- 3082

UN No. (ICAO) --------------------3082

14.2. UN proper shipping name

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,  LIQUID,  N.O.S. (PIPERONYL BUTOXIDE,  

PYRETHRINS INCLUDING CINERINS)

14.3. Transport hazard class(es)

ADR/RID/ADN------------------- Class 9

ADR/RID/ADN Class------------ Class 9: Miscellaneous dangerous substances and articles.

ADR Label No.--------------------- 9

IMDG Class -------------------------9

ICAO Class/Division--------------- 9

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Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group------- III

IMDG Packing group------------------ III

ICAO Packing group ------------------III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

EMS------------------------------- F-A,  S-F

Emergency Action Code -------3Z

Hazard No. (ADR)-------------- 90

Hazard No. (ADR)-------------90  Environmentally hazardous substance; miscellaneous dangerous substances.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

 

SECTION 15: REGULATORY INFORMATION

 

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

Revision Comments

Safety phrase update.

Issued By Nancy Hu.

Revision Date 12/06/2008

Date 17/02/2017

Risk Phrases In Full

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 Harmful: may cause lung damage if swallowed.

R38 Irritating to skin.

R41 Risk of serious damage to eyes.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any

process.  Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty

guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such

information for his own particular use.

 


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